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测量与信息技术

张国雄

《中国工程科学》 2000年 第2卷 第3期   页码 62-66

摘要：

测量是获取信息的重要手段。科学研究、生产、高科技发展都离不开测量。测量技术发展的重要特点是它与信息技术的融合，这是提高测量精度、在线和动态测量、复杂参数和复杂环境下测量、智能测量的需要。这一融合贯穿始终，它包括信号调制与解调、采样与重构、信号融合、数据压缩、滤波、信号变换、时间序列分析、谱分析、数据拟合与建模、模式识别、神经网络、仿真与虚拟、误差分离、误差补偿、冗余技术、决策与智能技术等，它们互相支持。文章通过三坐标测量机误差补偿、圆度和轴系误差测量，以及大型工程的柔性坐标测量系统，介绍其在提高测量精度、优化、自标定、丢失信息自恢复、系统重组等方面的作用及其关键技术。

关键词： 测量     信息技术     误差补偿     建模     冗余技术     误差分离    

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Purification of ice structuring protein complexes from winter wheat using Triton X-114 phase partitioning

Huaneng XU, Haiying CHEN, Weining HUANG,

《化学科学与工程前沿（英文）》 2009年 第3卷 第4期   页码 383-385 doi: 10.1007/s11705-009-0249-7

摘要： Ice structuring proteins (ISPs) isolated from the cold-acclimated plants have a great potential in improving the quality of frozen foods. The purification of ISP complexes from winter wheat was achieved using an aqueous two-phase system of Triton X-114. The highly reactive phenols were removed, and the ISP complexes remained in the aqueous phase after phase separation. The ISP complexes treated by this procedure retained higher thermal hysteresis activity than those treated by ammonium sulfate method. The phase separation technique provides a simple and mild way for removing phenols from ISP complexes.

关键词： separation technique     thermal hysteresis     cold-acclimated     purification     X-114    

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Phase separation in cGAS-STING signaling

《医学前沿（英文）》   页码 855-866 doi: 10.1007/s11684-023-1026-6

摘要： Biomolecular condensates formed by phase separation are widespread and play critical roles in many physiological and pathological processes. cGAS-STING signaling functions to detect aberrant DNA signals to initiate anti-infection defense and antitumor immunity. At the same time, cGAS-STING signaling must be carefully regulated to maintain immune homeostasis. Interestingly, exciting recent studies have reported that biomolecular phase separation exists and plays important roles in different steps of cGAS-STING signaling, including cGAS condensates, STING condensates, and IRF3 condensates. In addition, several intracellular and extracellular factors have been proposed to modulate the condensates in cGAS-STING signaling. These studies reveal novel activation and regulation mechanisms of cGAS-STING signaling and provide new opportunities for drug discovery. Here, we summarize recent advances in the phase separation of cGAS-STING signaling and the development of potential drugs targeting these innate immune condensates.

关键词： biomolecular condensates     phase separation     cGAS-STING pathway     cGAS     STING     cGAMP     interferon    

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Selective capture and separation of xenon and krypton using metal organic frameworks: a review

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 1895-1912 doi: 10.1007/s11705-023-2355-3

摘要： Xenon and krypton are widespread useful noble gases in commercial lighting, lasers, electronics, and medical industry. At the same time, radioactive noble gases may proliferate from used nuclear fuel and diffuse in open atmospheres. Metal organic frameworks as hotspot porous materials for gases uptake and separation are considered to be potential solutions. In this review, we comprehensively summarized recent researches on metal organic frameworks for selective capture and separation of xenon and krypton. Particularly, we followed the aspects of different optimal design strategies, including optimal pore/cage size and geometry, open metal sites, ions (anions and cations), and polar functional groups for enhancing the xenon adsorption and separation performances. Meanwhile, a comparison of each strategy and the mechanisms of xenon/krypton separation were pointed out. The separation of krypton from gases mixtures by dual-bed systems was further discussed. Finally, some existing challenges and opportunities for possible real applications were proclaimed.

关键词： metal organic frameworks     xenon     krypton     selective separation     used nuclear fuel    

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General modeling and optimization technique for real-world earth observation satellite scheduling

《工程管理前沿（英文）》   页码 695-709 doi: 10.1007/s42524-023-0263-3

摘要： Over the last two decades, many modeling and optimization techniques have been developed for earth observation satellite (EOS) scheduling problems, but few of them show good generality to be engineered in real-world applications. This study proposes a general modeling and optimization technique for common and real-world EOS scheduling cases; it includes a decoupled framework, a general modeling method, and an easy-to-use algorithm library. In this technique, a framework that decouples the modeling, constraints, and optimization of EOS scheduling problems is built. With this framework, the EOS scheduling problems are appropriately modeled in a general manner, where the executable opportunity, another format of the well-known visible time window per EOS operation, is viewed as a selectable resource to be optimized. On this basis, 10 types of optimization algorithms, such as Tabu search and genetic algorithm, and a parallel competitive memetic algorithm, are developed. For simplified EOS scheduling problems, the proposed technique shows better performance in applicability and effectiveness than the state-of-the-art algorithms. In addition, a complicatedly constrained real-world benchmark exampled by a four-EOS Chinese commercial constellation is provided, and the technique is qualified and outperforms the in-use scheduling system by more than 50%.

关键词： earth observation satellite     scheduling     general technique     optimization algorithm     commercial constellation     real-world     benchmark    

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Highly hydrophobic oil−water separation membrane: reutilization of waste reverse osmosis membrane

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1606-1615 doi: 10.1007/s11705-022-2200-0

摘要： The increasing applications of seawater desalination technology have led to the wide usage of polyamide reverse osmosis membranes, resulting in a large number of wasted reverse osmosis membranes. In this work, the base nonwoven layer of the wasted reverse osmosis membrane was successfully modified into the hydrophobic membrane via surface deposition strategy including TiO2 and 1H,1H,2H,2H-perfluorooctyltrichlorosilane (PFOTS), respectively. Various techniques were applied to characterize the obtained membranes, which were then used to separate the oil–water system. The optimally modified membrane displayed good hydrophobicity with a contact angle of 135.2° ± 0.3°, and its oil–water separation performance was as high as 97.8%. After 20 recycle tests, the oil–water separation performance remained more than 96%, which was attributed to the film adhesion of the anchored TiO2 and PFOTS layer on the surface. This work might provide a new avenue for recycling the wasted reverse osmosis membrane used in oily wastewater purification.

关键词： oil–water separation     wasted reverse osmosis membrane     hydrophobic modification    

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Phase separation time/temperature dependence of thermoplastics-modified thermosetting systems

ZHANG Xiujuan, XU Yuanze, YI Xiaosu

《化学科学与工程前沿（英文）》 2008年 第2卷 第3期   页码 276-285 doi: 10.1007/s11705-008-0057-5

摘要： The cure-induced phase separation processes of various thermoplastics(TP)-modified thermosetting systems which show upper critical solution temperature (UCST) or lower critical solution temperature (LCST) were studied with emphasis on the temperature dependency of the phase separation time and its potential application in the cure time-temperature processing window. We found that the phase separation time/temperature relationship follows the simple Arrhenius equation. The cure-induced phase separation activation energy (ps) generated from the linear fitting of the Arrhenius equation is irrelevant to the detection means of phase separation time. We also found that (ps) is insensitive to TP content, TP molecular weight and curing rate, but it changes with the cure reaction kinetics and the chemical environment of the systems. With the established phase separation time-temperature dependence relation, we can easily establish the whole cure time-temperature transformation (TTT) diagram with morphology information which is a useful map for the TP/TS composites processing industry.

关键词： separation time-temperature     temperature dependency     cure-induced     separation activation     temperature    

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Microfluidic production of liposomes through liquid–liquid phase separation in ternary droplets

《化学科学与工程前沿（英文）》 2022年 第16卷 第6期   页码 1017-1022 doi: 10.1007/s11705-021-2118-y

摘要： Liposomes, the self-assembled phospholipid vesicles, have been extensively used in various fields such as artificial cells, drug delivery systems, biosensors and cosmetics. However, current microfluidic routes to liposomes mostly rely on water-in-oil-in-water double emulsion droplets as templates, and require complex fabrication of microfluidic devices, and tedious manipulation of multiphase fluids. Here we present a simple microfluidic approach to preparing monodisperse liposomes from oil-in-water droplets. For demonstration, we used butyl acetate-water-ethanol ternary mixtures as inner phase and an aqueous solution of surfactants as outer phase to make oil-in-water droplets, which can evolve into water-in-oil-in-water double emulsion droplets by liquid–liquid phase separation of ternary mixtures. Subsequently, the resultant water-in-oil-in-water droplets underwent a dewetting transition to form separated monodisperse liposomes and residual oil droplets, with the assistance of surfactants. The method is simple, does not require complex microfluidic devices and tedious manipulation, and provides a new platform for controllable preparation of liposomes.

关键词： microfluidics     liposomes     ternary droplets     phase separation    

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Imprinted membranes for sustainable separation processes

Laura Donato, Enrico Drioli

《化学科学与工程前沿（英文）》 2021年 第15卷 第4期   页码 775-792 doi: 10.1007/s11705-020-1991-0

摘要： The rapid industrial growth and the necessity of recovering and recycling raw materials increased the interest in the production of highly selective and efficient separation tools. In this perspective, a relevant input was given by the membrane-based technology and the production of imprinted membranes, which possess specific recognition properties at molecular and ionic level, offers the possibility of developing sustainable and green processes. Furthermore, the integration of imprinted membranes with traditional or membrane-based approaches is a promising strategy in the logic of process intensification, which means the combination of different operations in a single apparatus. This work discusses the concept and separation mechanisms of imprinted membranes. Furthermore, it presents an overview of their application in organic solvent nanofiltration, for the removal of toxic agents and recovery solvent, as well as valuable compounds. The recent advances in water treatment, such as pesticide removal and recovery of metal ions, are also discussed. Finally, potential applications of imprinted membranes in hybrid processes are highlighted, and a look into the future of membrane separations for water treatment and recovery of critical raw materials is offered.

关键词： sustainable processes     membrane separation     molecular recognition     imprinted membranes     water treatment    

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Fabrication of a superhydrophilic/underwater superoleophobic stainless steel mesh for oil/water separation

《化学科学与工程前沿（英文）》 2023年 第17卷 第1期   页码 46-55 doi: 10.1007/s11705-022-2170-2

摘要： Because of the increasing amount of oily wastewater produced each day, it is important to develop superhydrophilic/underwater superoleophobic oil/water separation membranes with ultrahigh flux and high separation efficiency. In this paper, a superhydrophilic/underwater superoleophobic N-isopropylacrylamide-coated stainless steel mesh was prepared through a simple and convenient graft polymerization approach. The obtained mesh was able to separate oil/water mixtures only by gravity. In addition, the mesh showed high-efficiency separation ability (99.2%) and ultrahigh flux (235239 L∙m–2∙h–1). Importantly, due to the complex cross-linked bilayer structure, the prepared mesh exhibited good recycling performance and chemical stability in highly saline, alkaline and acidic environments.

关键词： oil/water separation     N-isopropylacrylamide     stainless steel mesh     ultrahigh flux    

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Easily-manufactured paper-based materials with high porosity for adsorption/separation applications in

《化学科学与工程前沿（英文）》 2023年 第17卷 第7期   页码 830-839 doi: 10.1007/s11705-022-2267-7

摘要： A multi-functional porous paper-based material was prepared from grass pulp by simple pore-forming and green cross-linking method. As a pore-forming agent, calcium citrate increased the porosity of the paper-based material from 30% to 69% while retaining the mechanical strength. The covalent cross-linking of citric acid between cellulose fibers improved both the wet strength and adsorption capacity. In addition, owing to the introduction of high-content carboxyl groups as well as the construction of hierarchical micro-nano structure, the underwater oil contact angle was up to 165°. The separation efficiency of the emulsified oil was 99.3%, and the water flux was up to 2020 L·m–2·h–1. The theoretical maximum adsorption capacities of cadmium ion, lead ion and methylene blue reached 136, 229 and 128.9 mg·g–1, respectively. The continuous purification of complex wastewater can be achieved by using paper-based materials combined with filtration technology. This work provides a simple, low cost and environmental approach for the treatment of complex wastewater containing insoluble oil, organic dyes, and heavy metal ions.

关键词： adsorption     oil–water separation     underwater superoleophobicity     wastewater treatment    

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Biodegradable, superhydrophobic walnut wood membrane for the separation of oil/water mixtures

《化学科学与工程前沿（英文）》 2022年 第16卷 第9期   页码 1377-1386 doi: 10.1007/s11705-022-2157-z

摘要： The preparation of environmentally friendly oil/water separation materials remains a great challenge. Freeze-drying of wood after lignin removal yields wood aerogels, which can be used as substrates to prepare fluorine-free environmentally friendly superhydrophobic materials, However, they are more suitable for absorption rather than filtration applications due to their poor strength. A study using cross-sections of pristine wood chips as substrates retains the original strength of wood, but the use of the cross-sectional of wood pieces limits their thickness, strength, and size. In this paper, a degradable fluorine-free superhydrophobic film (max. water contact angle of approximately 164.2°) with self-cleaning and abrasion resistance characteristics was prepared by a one-step method using pristine and activated walnut longitudinal section films as the substrate, with tetraethyl orthosilicate as a precursor and dodecyltriethoxysilane as a modifier. The tensile strength results show that superhydrophobic films with pristine or activated wood substrates maintained the strength of pristine wood and were 2.2 times stronger than the wood aerogel substrate. In addition, after cross-laminating the two samples, the films had the ability to separate oil and water by continuous filtration with high efficiency (98.5%) and flux (approximately 1.3 × 103 L∙m‒2∙h‒1). The method has potential for the large-scale fabrication of degradable superhydrophobic filtration separation membranes.

关键词： wood nanotechnology     superhydrophobic     biodegradable     surface modification     oil/water separation    

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Rare-earth separation based on the differences of ionic magnetic moment via quasi-liquid strategy

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1584-1594 doi: 10.1007/s11705-022-2189-4

摘要： The separation of rare earth elements is particularly difficult due to their similar physicochemical properties. Based on the tiny differences of ionic radius, solvent extraction has been developed as the “mass method” in industry with hundreds of stages, extremely intensive chemical consumption and large capital investments. The differences of the ionic magnetic moment among rare earths are greater than that of ionic radius. Herein, a novel method based on the large ionic magnetic moment differences of rare earth elements was proposed to promote the separation efficiency. Rare earths were firstly dissolved in the ionic liquid, then the ordering degree of them was improved with the Z-bond effect, and finally the magnetic moment differences between paramagnetic and diamagnetic rare earths in quasi-liquid system were enhanced. Taking the separation of Er/Y, Ho/Y and Er/Ho as examples, the results showed that Er(III) and Ho(III) containing ionic liquids had obvious magnetic response, while ionic liquids containing Y(III) had no response. The separation factors of Er/Y and Ho/Y were achieved at 9.0 and 28.82, respectively. Magnetic separation via quasi-liquid system strategy provides a possibility of the novel, green, and efficient method for rare earth separation.

关键词： rare earth element     different magnetic moment     magnetic separation     ionic liquid    

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Mechanism of ethanol/water reverse separation through a functional graphene membrane: a molecular simulation

《化学科学与工程前沿（英文）》 2023年 第17卷 第3期   页码 347-357 doi: 10.1007/s11705-022-2246-z

摘要： Reverse-selective membranes have attracted considerable interest for bioethanol production. However, to date, the reverse-separation performance of ethanol/water is poor and the separation mechanism is unclear. Graphene-based membranes with tunable apertures and functional groups have shown substantial potential for use in molecular separation. Using molecular dynamics simulations, for the first time, we reveal two-way selectivity in ethanol/water separation through functional graphene membranes. Pristine graphene (PG) exhibits reverse-selective behavior with higher ethanol fluxes than water, resulting from the preferential adsorption for ethanol. Color flow mappings show that this ethanol-permselective process is initiated by the presence of ethanol-enriched and water-barren pores; this has not been reported in previous studies. In contrast, water molecules are preferred for hydroxylated graphene membranes because of the synergistic effects of molecular sieving and functional-group attraction. A simulation of the operando condition shows that the PG membrane with an aperture size of 3.8 Å achieves good separation performance, with an ethanol/water separation factor of 34 and a flux value of 69.3 kg∙m‒2∙h‒1∙bar‒1. This study provides new insights into the reverse-selective mechanism of porous graphene membranes and a new avenue for efficient biofuel production.

关键词： reverse separation     graphene membrane     ethanol/water separation     molecular simulation    

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Modeling of the separation performance of nanofiltration membranes and its role in the applications ofnanofiltration technology in product separation processes

SHANG Weijuan, WANG Daxin, WANG Xiaolin

《化学科学与工程前沿（英文）》 2007年 第1卷 第2期   页码 208-215 doi: 10.1007/s11705-007-0038-0

摘要： Although there is a voluminous literature on the determination of structural parameters (the pore radius, the ratio of membrane porosity to membrane thickness) of a nanofiltration (NF) membrane and its separation performance (such as the rejection and the permeation flux) by the simplified Teorell-Meyer-Sievers (TMS) model, little of this research comments on other theories and the consequences of linking modeling evaluation to technological application. Theories used to predict the separation performance of an NF membrane usually include: the non-equilibrium thermodynamic model, the pore model, the space charge model, the TMS model, the electrostatic and steric-hindrance model, and the semiempirical model. In the article, we briefly trace the origins or the general ideas of the above-mentioned theories. From there, recent researches on the characterization of membrane structural parameters and electrical properties (such as the surface charge density ) are reviewed. We then turn to research on the separation performance of an NF membrane for single-component solutions of inorganic electrolytes, neutral organic solutions, and a mixture solution of electrolytes or that of an electrolyte and neutral organic solute. Afterwards, we outline the applications of NF technology in the processes of product separation and conclude with a discussion on the role of models in such applications.

关键词： above-mentioned     TMS     characterization     electrostatic     semiempirical    

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标题 作者 时间 类型 操作

测量与信息技术

张国雄

期刊论文

Purification of ice structuring protein complexes from winter wheat using Triton X-114 phase partitioning

Huaneng XU, Haiying CHEN, Weining HUANG,

期刊论文

Phase separation in cGAS-STING signaling

期刊论文

Selective capture and separation of xenon and krypton using metal organic frameworks: a review

期刊论文

General modeling and optimization technique for real-world earth observation satellite scheduling

期刊论文

Highly hydrophobic oil−water separation membrane: reutilization of waste reverse osmosis membrane

期刊论文

Phase separation time/temperature dependence of thermoplastics-modified thermosetting systems

ZHANG Xiujuan, XU Yuanze, YI Xiaosu

期刊论文

Microfluidic production of liposomes through liquid–liquid phase separation in ternary droplets

期刊论文

Imprinted membranes for sustainable separation processes

Laura Donato, Enrico Drioli

期刊论文

Fabrication of a superhydrophilic/underwater superoleophobic stainless steel mesh for oil/water separation

期刊论文

Easily-manufactured paper-based materials with high porosity for adsorption/separation applications in

期刊论文

Biodegradable, superhydrophobic walnut wood membrane for the separation of oil/water mixtures

期刊论文

Rare-earth separation based on the differences of ionic magnetic moment via quasi-liquid strategy

期刊论文

Mechanism of ethanol/water reverse separation through a functional graphene membrane: a molecular simulation

期刊论文

Modeling of the separation performance of nanofiltration membranes and its role in the applications ofnanofiltration technology in product separation processes

SHANG Weijuan, WANG Daxin, WANG Xiaolin

期刊论文